Preheat the oven to 325 degrees Fahrenheit.
Spray a 10-inch springform pan with oil or coat the sides and bottom with butter. Line the bottom with parchment. Spray or coat the parchment paper with oil as well, then dust the pan with 2 tablespoon cocoa flour.
Whisk together the all purpose flour, tapioca flour, baking powder, baking soda, salt, ground black pepper and cloves in a large bowl. Set aside.
In a saucepan place the remaining ¾ cup cocoa powder, butter, instant coffee, water, whiskey, sugar and maple syrup. Whisk and set over low heat. Continue whisking until all of the sugar and butter has melted.
Once the cocoa-butter-coffee mixture has cooled, add to it the aquafaba and the pure vanilla extract. Mix, then pour into the bowl with the flour and other dry ingredients.
Mix with a spatula or whisk until combined. Stir in the chocolate chips. This batter is a bit more liquid that a typical cake batter, but that's how it should be.
Place the prepared springform pan on a baking sheet, then pour the cake batter into it.
Place in the oven and bake 1 hour or until a toothpick or skewer in the center comes out clean.
Place the cake on a rack and let it cool. Unmold--run a knife along the sides of the cake if necessary. Dust the cake with powdered sugar and serve.